The PbO2 Titanium Anode produced by Baoji Changsheng Titanium Co., Ltd. After acid etching of the titanium substrate, a gradient oxide substrate layer is prepared by thermal decomposition method, and then electroplated the middle layer of α-PbO2 in an alkaline solution, and then prepare the surface layer of β-PbO2 including fluorine, which are particles doped with an active metal and a high adsorption performance, then the surface is cleaned and dried to obtain a new type of titanium based Lead dioxide electrode. The PbO2 Titanium Anode prepared by the method has low price and long service life. The Lead dioxide electrode based on titanium mesh can reduce the flow resistance of electrolyte and improve the current efficiency, it can effectively prevent the electrode from overheating.